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JEE Main 202228 JuneEvening Shift
Exam
JEE Main
Year
2022
Date
28 June
Shift
Evening Shift
Subject
Chemistry
Chapter
Ionic Equilibrium

JEE Main 2022 · 28 June · Evening Shift · Chemistry · Ionic Equilibrium

A student needs to prepare a buffer solution of propanoic acid and...

A student needs to prepare a buffer solution of propanoic acid and its sodium salt with pH4pH4. The ratio of \dfrac{\left[{\text{ CH }}_{3}{\text{ CH }}_{2}{\text{ COO }}^{-}\right]}{\left[{CH}_{3}{CH}_{2}COOH\right]} required to make buffer is Given : Ka(CH3CH2COOH)=1.3×10−5{K}_{a}\left({CH}_{3}{CH}_{2}COOH\right) = 1 . 3 \times {10}^{- 5}

Options

  1. A0.030 . 03
  2. B0.130 . 13
  3. C0.230 . 23
  4. D0.330 . 33

Correct answer

B. 0.130 . 13

Step-by-step solution

Henderson's equation for calculating pH of acidic buffer solutions is given as

pH=pKa+log⁡([Salt][Acid])pH = {pK}_{a} + \log \left(\dfrac{\left[Salt\right]}{\left[Acid\right]}\right)

pH=pKa+log⁡([CH3COO−][CH3COOH])pH = {pK}_{a} + \log \left(\dfrac{\left[{CH}_{3}{COO}^{-}\right]}{\left[{CH}_{3}COOH\right]}\right)

4=5−log⁡(1.3)+log⁡([CH3COO−][CH3COOH])4 = 5 - \log ( 1 . 3 ) + \log \left(\dfrac{\left[{CH}_{3}{COO}^{-}\right]}{\left[{CH}_{3}COOH\right]}\right)

log⁡(1.3×10−1)=log⁡([CH3COO−][CH3COOH])\log \left(1 . 3 \times {10}^{- 1}\right) = \log \left(\dfrac{\left[{CH}_{3}{COO}^{-}\right]}{\left[{CH}_{3}COOH\right]}\right)

[CH3COO−][CH3COOH]=0.13\dfrac{\left[{CH}_{3}{COO}^{-}\right]}{\left[{CH}_{3}COOH\right]} = 0 . 13

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