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JEE Main 202117 MarchMorning Shift
Exam
JEE Main
Year
2021
Date
17 March
Shift
Morning Shift
Subject
Chemistry
Chapter
Ionic Equilibrium

JEE Main 2021 · 17 March · Morning Shift · Chemistry · Ionic Equilibrium

0 . 01 moles of a weak acid H A( K _ a = 2 . 0 × 10 ^ - 6 ) is...

0 . 01molesofaweakacidmoles of a weak acidHA(Ka=2.0×10−6)A\left({K}_{a} = 2 . 0 \times {10}^{- 6}\right) is dissolved in 1.0L1 . 0L of 0.1MHCl0 . 1MHCl solution. The degree of dissociation of HAHA is __________ ×10−5\times {10}^{- 5} (Round off to the Nearest Integer). [Neglect volume change on adding HAHA and assume degree of dissociation <<1< < 1]

Correct answer

0

Step-by-step solution

{HA⇌H++A−Initial conc.0.1M0MEqu. conc.(0.01−x)(0.1+x)xM≈0.01M≈0.1M\begin{cases}HA ⇌ {H}^{+} + & {A}^{-} & \\ \text{Initial conc.} & 0 . 1M & 0M & \\ \text{Equ. conc.} & ( 0 . 01 - x ) ( 0 . 1 + x ) & xM & \\ \approx 0 . 01M \approx 0 . 1M & \end{cases}

Now, Ka=[H+][A−][HA]⇒2×10−6=0.1×x0.01{K}_{a} = \dfrac{\left[{H}^{+}\right]\left[{A}^{-}\right]}{[ HA ]} ⇒ 2 \times {10}^{- 6} = \dfrac{0 . 1 \times x}{0 . 01}

∴x=2×10−7∴ x = 2 \times {10}^{- 7}

Now, α=x0.01=2×10−70.01=2×10−5\alpha = \dfrac{x}{0 . 01} = \dfrac{2 \times {10}^{- 7}}{0 . 01} = 2 \times {10}^{- 5}

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