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JEE Main 202116 MarchMorning Shift
Exam
JEE Main
Year
2021
Date
16 March
Shift
Morning Shift
Subject
Chemistry
Chapter
Ionic Equilibrium

JEE Main 2021 · 16 March · Morning Shift · Chemistry · Ionic Equilibrium

Two salts A _ 2 X and MX have the same value of solubility product...

Two salts A2X{A}_{2}X and MXMX have the same value of solubility product of 4.0×10−124 . 0 \times {10}^{- 12}. The ratio of their molar solubilizes i.e. S(A2X)S(MX)=\dfrac{S\left({A}_{2}X\right)}{S ( MX )} = ________.

(Round off to the Nearest Integer).

Correct answer

0

Step-by-step solution

For A2X{A}_{2}X

{A2X→2A++X2−2S1S1\begin{cases}{A}_{2}X & \to & 2{A}^{+} & + & {X}^{2 -} \\ 2{S}_{1} & {S}_{1}\end{cases}Ksp=4S13=4×10−12{K}_{sp} = 4{S}_{1}^{3} = 4 \times {10}^{- 12}

S1=10−4{S}_{1} = {10}^{- 4}

for MXMX

{MX→M++X−S2S2\begin{cases}MX & \to & {M}^{+} & + & {X}^{-} \\ {S}_{2} & {S}_{2}\end{cases}

Ksp=S22=4×10−12{K}_{sp} = {S}_{2}^{2} = 4 \times {10}^{- 12}

S2=2×10−6{S}_{2} = 2 \times {10}^{- 6}

So SA2xSMX=10−42×10−6=50\dfrac{{S}_{{A}_{2}x}}{{S}_{MX}} = \dfrac{{10}^{- 4}}{2 \times {10}^{- 6}} = 50

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