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JEE Main 20253 AprilEvening Shift
Exam
JEE Main
Year
2025
Date
3 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Redox Reactions

JEE Main 2025 · 3 April · Evening Shift · Chemistry · Redox Reactions

Compounds that should not be used as primary standards in...

Compounds that should not be used as primary standards in titrimetric analysis are :
A. Na2Cr2O7\mathrm{Na}_2 \mathrm{Cr}_2 \mathrm{O}_7
B. Oxalic acid
C. NaOH
D. FeSO4⋅6H2O\mathrm{FeSO}_4 \cdot 6 \mathrm{H}_2 \mathrm{O}
E. Sodium tetraborate
Choose the most appropriate answer from the options given below:

Options

  1. AB and D Only
  2. BD and E Only
  3. CC, D and E Only
  4. DA, C and D Only

Correct answer

D. A, C and D Only

Step-by-step solution

The primary standard is a highly pure stable compound with a known exact composition that can be accurately weighed and dissolved to creat a solution of known concentration.
NaOH is hygroscopic and can't be used.
FeSO4⋅6H2O\mathrm{FeSO}_4 \cdot 6 \mathrm{H}_2 \mathrm{O} is unstable and can be easily oxidised.
Na2Cr2O7\mathrm{Na}_2 \mathrm{Cr}_2 \mathrm{O}_7 is hygroscopic and can't be used.
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