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JEE Main 202431 JanuaryEvening Shift
Exam
JEE Main
Year
2024
Date
31 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Redox Reactions

JEE Main 2024 · 31 January · Evening Shift · Chemistry · Redox Reactions

Given below are two statements : Statement I: S _ 8 solid undergoes...

Given below are two statements :

Statement I: S8{S}_{8} solid undergoes disproportionation reaction under alkaline conditions to form S2−{S}^{2 -} and S2O32−{S}_{2}{O}_{3}^{2 -}

Statement II: ClO4−{ClO}_{4}^{-} can undergo disproportionation reaction under acidic condition.

In the light of the above statements, choose the most appropriate answer from the options given below:

Options

  1. AStatement I is correct but statement II is incorrect.
  2. BStatement I is incorrect but statement II is correct
  3. CBoth statement I and statement II are incorrect
  4. DBoth statement I and statement II are correct

Correct answer

A. Statement I is correct but statement II is incorrect.

Step-by-step solution

A disproportionation reaction is a reaction in which the same element is simultaneously oxidized and reduced. In this type of reaction, a single substance gives two products, one is oxidized while the other is reduced.

S1:S8+12OH⊝→4S2−+2S2O32−+6H2O{S}_{1}: {S}_{8} + 12{OH}^{⊝} \to 4{S}^{2 -} + 2{S}_{2}{O}_{3}^{2 -} + 6{H}_{2}O

S2:ClO4⊝{S}_{2}: {ClO}_{4}^{⊝} cannot undergo disproportionation reaction as chlorine is present in its highest oxidation state.

Hence, statement II is correct and IIII is incorrect.

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