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JEE Main 202430 JanuaryMorning Shift
Exam
JEE Main
Year
2024
Date
30 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Redox Reactions

JEE Main 2024 · 30 January · Morning Shift · Chemistry · Redox Reactions

2 MnO _ 4 ^ - + bI ^ - + cH _ 2 O → xI _ 2 + yMnO _ 2 + zOH ^ - If...

2MnO4−+bI−+cH2O→xI2+yMnO2+zOH−2{MnO}_{4}^{-} + {bI}^{-} + {cH}_{2}O \to {xI}_{2} + {yMnO}_{2} + {zOH}^{-}

If the above equation is balanced with integer coefficients, the value of zz is ________.

Correct answer

0

Step-by-step solution

Reduction Half reaction

2MnO4−→2MnO22{MnO}_{4}^{-} \to 2{MnO}_{2}

2MnO4−+4H2O+6e−→2MnO2+8OH−2{MnO}_{4}^{-} + 4{H}_{2}O + 6{e}^{-} \to 2{MnO}_{2} + 8{OH}^{-}

Oxidation Half reaction

2I−→I2+2e−2{I}^{-} \to {I}_{2} + 2{e}^{-}

6I−→3I2+6e−6{I}^{-} \to 3{I}_{2} + 6{e}^{-}

Adding oxidation half and reduction half, net reaction is

2MnO4−+6I−+4H2O→3I2+2MnO2+8OH−2{MnO}_{4}^{-} + 6{I}^{-} + 4{H}_{2}O \to 3{I}_{2} + 2{MnO}_{2} + 8{OH}^{-}

⇒z=8⇒ z = 8

⇒Ans8⇒ Ans8

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