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JEE Main 202313 AprilMorning Shift
Exam
JEE Main
Year
2023
Date
13 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Redox Reactions

JEE Main 2023 · 13 April · Morning Shift · Chemistry · Redox Reactions

20mL of calcium hydroxide was consumed when it was reacted with...

20mL20mL of calcium hydroxide was consumed when it was reacted with 10mL10mL of unknown solution of H2SO4.{H}_{2}{SO}_{4} . Also 20mL20mL standard solution of 0.5MHCl0 . 5MHCl containing 22 drops of phenolphthalein was titrated with calcium hydroxide, the mixture showed pink colour when burette displayed the value of 35.5mL35 . 5mL whereas the burette showed 25.5mL25 . 5mL initially. The concentration of H2SO4{H}_{2}{SO}_{4} is _______M . (Nearest integer)

Correct answer

0

Step-by-step solution

Titration principle is N1V1=N2V2{N}_{1}{V}_{1} = {N}_{2}{V}_{2}

N = Normality

V = Volume of solution

M1V1n1=M2V2n2{M}_{1}{V}_{1}{n}_{1} = {M}_{2}{V}_{2}{n}_{2}

M = molarity

n = Valence factor of acid or base

As pink colour is obtained on consumption of 10ml10ml of Ca(OH)2,Ca ( OH{)}_{2}, we have

20×0.5×1=10×M×220 \times 0 . 5 \times 1 = 10 \times M \times 2

Molarity of Ca(OH)2=1020=12MCa ( OH{)}_{2} = \dfrac{10}{20} = \dfrac{1}{2}M

Also, moles of Ca(OH)2=mmCa ( OH{)}_{2} = mm of H2SO4{H}_{2}{SO}_{4}

12×20=10×M\dfrac{1}{2} \times 20 = 10 \times M

Molarity of H2SO4=1M{H}_{2}{SO}_{4} = 1M

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