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JEE Main 202324 JanuaryEvening Shift
Exam
JEE Main
Year
2023
Date
24 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Redox Reactions

JEE Main 2023 · 24 January · Evening Shift · Chemistry · Redox Reactions

Choose the correct representation of conductometric titration of...

Choose the correct representation of conductometric titration of benzoic acid vs sodium hydroxide.Choose the correct representation of conductometric titration of benzoic acid vs sodium hydroxide.Choose the correct representation of conductometric titration of benzoic acid vs sodium hydroxide.Choose the correct representation of conductometric titration of benzoic acid vs sodium hydroxide.Choose the correct representation of conductometric titration of benzoic acid vs sodium hydroxide.Choose the correct representation of conductometric titration of benzoic acid vs sodium hydroxide.

Options

  1. AA petroleum fraction having boiling range 70 - 200^ o C and containing 6 - 10 carbon atoms per molecule is called
  2. BA petroleum fraction having boiling range 70 - 200^ o C and containing 6 - 10 carbon atoms per molecule is called
  3. CA petroleum fraction having boiling range 70 - 200^ o C and containing 6 - 10 carbon atoms per molecule is called
  4. DA petroleum fraction having boiling range 70 - 200^ o C and containing 6 - 10 carbon atoms per molecule is called

Correct answer

B. A petroleum fraction having boiling range 70 - 200^ o C and containing 6 - 10 carbon atoms per molecule is called

Step-by-step solution

C6H5C(WA)OOH+NaO(SB)H→C6H5C(Salt)OONa+H2O{C}_{6}{H}_{5}\mathop{C}_{\left(WA\right)}OOH + Na\mathop{O}_{\left(SB\right)}H \to {C}_{6}{H}_{5}\mathop{C}_{\left(Salt\right)}OONa + {H}_{2}O

Choose the correct representation of conductometric titration of benzoic acid vs sodium hydroxide.

Initially the conductance is low due to the feeble ionisation of acetic acid. On the addition of base, there is decrease in conductance(A→BA \to B) not only due to the replacement ofH+{H}^{+} by Na+{Na}^{+} but also suppresses the dissociation of benzoic acid due to common ion benzoate. But very soon, the conductance increases(B→CB \to C) on adding NaOHNaOH as NaOHNaOH neutralises the un-dissociated C6H5COOH{C}_{6}{H}_{5}COOH to C6H5COONa{C}_{6}{H}_{5}COONa which is the strong electrolyte. This increase in conductance continues raise up to the equivalence point. The graph near the equivalence point is curved due the hydrolysis of salt C6H5COONa{C}_{6}{H}_{5}COONa. Beyond the equivalence point, conductance increases(C→DC \to D) more rapidly with the addition of NaOHNaOH due to the highly conducting OH−{OH}^{-} ions

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