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JEE Main 202228 JulyEvening Shift
Exam
JEE Main
Year
2022
Date
28 July
Shift
Evening Shift
Subject
Chemistry
Chapter
Redox Reactions

JEE Main 2022 · 28 July · Evening Shift · Chemistry · Redox Reactions

Given below are two statements: One is labelled as Assertion A and...

Given below are two statements: One is labelled as Assertion AA and the other is labelled as Reason RR

Assertion AA : Permanganate titration are not performed in presence of hydrochloric acid.

Reason RR : Chlorine is formed as a consequence of oxidation of hydrochloric acid.

In the light of the above statements, choose the correct answer from the options given below

Options

  1. ABoth AA and RR are true and RR is the correct explanation of AA
  2. BBoth AA and RR are true but RR is NOT the correct explanation of AA
  3. CAA is true but RR is false
  4. DAA is false but RR is true

Correct answer

A. Both AA and RR are true and RR is the correct explanation of AA

Step-by-step solution

Hydrochloric acid (HCl) is usually not used in the process of titration because it reacts with the indicator potassium permanganate (KMnO4)( {KMnO}_{4} ) that is used in the process. It reacts with KMnO4{KMnO}_{4} solution and gets oxidized which further results in the liberation of chlorine gas according to the following reaction.

2KMnO4+16HCl→2MnCl2+2KCl+8H2O+5Cl22{KMnO}_{4} + 16HCl \to 2{MnCl}_{2} + 2KCl + 8{H}_{2}O + 5{Cl}_{2}

So, Both AA and RR are true and RR is the correct explanation of AA

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