Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Main 202228 JuneMorning Shift
Exam
JEE Main
Year
2022
Date
28 June
Shift
Morning Shift
Subject
Chemistry
Chapter
Redox Reactions

JEE Main 2022 · 28 June · Morning Shift · Chemistry · Redox Reactions

A 2 . 0g sample containing MnO _ 2 is treated with HCl liberating...

A 2.0g2 . 0g sample containing MnO2{MnO}_{2} is treated with HClHCl liberating Cl2{Cl}_{2}. The Cl2{Cl}_{2} gas is passed into a solution of KIKI and 60.0mL60 . 0mL of 0.1MNaS2O30 . 1{MNaS}_{2}{O}_{3} is required to titrate the liberated iodine. The percentage of MnO2{MnO}_{2} in the sample is____. Nearest integer)
[Atomic masses (in uu) Mn=55;Cl=35.5:O=16,I=127,Na=23,K=39,S=32Mn = 55; Cl = 35 . 5: O = 16, I = 127, Na = 23, K = 39, S = 32]

Correct answer

0

Step-by-step solution

MnO2+4HCl⟶MnCl2+Cl2(g)+2H2O{MnO}_{2} + 4HCl ⟶ {MnCl}_{2} + {Cl}_{2}\left(g\right) + 2{H}_{2}O

Cl2+2Kl⟶I2+2KCl{Cl}_{2} + 2Kl ⟶ {I}_{2} + 2KCl

I2+2Na2S2O3⟶2Nal+Na2S4O6{I}_{2} + 2{Na}_{2}{S}_{2}{O}_{3} ⟶ 2Nal + {Na}_{2}{S}_{4}{O}_{6}

Mili eq. of MnO2={MnO}_{2} = Mili eq. of Cl2={Cl}_{2} = Mili eq. of I2={I}_{2} = Mili eq. of Hypo.

2(w87)=[0.1×60]2\left(\dfrac{w}{87}\right) = \left[0 . 1 \times 60\right]

W=261W = 261 miligram

% of{MnO}_{2} = \dfrac{0 . 261}{2} \times 100 = 13 . 05 % \approx 13

Practice Redox Reactions on Quantrex Academy →

More from Redox Reactions

500 mL of 0.2 M MnO _4^- solution in basic medium when mixed with 500 mL of 1.5 M KI… JEE Main 2026Given below are two statements: Statement I: Sodium dichromate and potassium dichromate… JEE Main 2026In order to oxidise a mixture of 1 mole each of FeC_2O_4 , Fe_2(C_2O_4)_3 , FeSO_4 and… JEE Main 2026500 mL of 1.2 M KI solution is mixed with 500 mL of 0.2 M KMnO_ 4 solution in basic… JEE Main 2026One mole of Cl_ 2 (~g) was passed into 2 L of cold 2 M KOH solution. After the reaction… JEE Main 2026X and Y are the number of electrons involved, respectively during the oxidation of I^… JEE Main 2026200 cc of x × 10^ -3 M potassium dichromate is required to oxidise 750 cc of 0.6 M Mohr's… JEE Main 2026Identify the correct statements : A. Hydrated salts can be used as primary standard. B.… JEE Main 2026 Full Redox Reactions list All JEE Main PYQs