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JEE Main 202131 AugustEvening Shift
Exam
JEE Main
Year
2021
Date
31 August
Shift
Evening Shift
Subject
Chemistry
Chapter
Redox Reactions

JEE Main 2021 · 31 August · Evening Shift · Chemistry · Redox Reactions

In which one of the following sets all species show...

In which one of the following sets all species show disproportionation reaction?

Options

  1. AClO4−,MnO4−,ClO2−{ClO}_{4}^{-}, {MnO}_{4}^{-}, {ClO}_{2}^{-}and F2{F}_{2}
  2. BMnO42−,ClO2−,Cl2{MnO}_{4}^{2 -}, {ClO}_{2}^{-}, {Cl}_{2} and Mn3+{Mn}^{3 +}
  3. CCr2O72−,MnO4−,ClO2−{Cr}_{2}{O}_{7}^{2 -}, {MnO}_{4}^{-}, {ClO}_{2}^{-} and Cl2{Cl}_{2}
  4. DClO2−,F2,MnO4−{ClO}_{2}^{-}, {F}_{2}, {MnO}_{4}^{-} and Cr2O72−{Cr}_{2}{O}_{7}^{2 -}

Correct answer

B. MnO42−,ClO2−,Cl2{MnO}_{4}^{2 -}, {ClO}_{2}^{-}, {Cl}_{2} and Mn3+{Mn}^{3 +}

Step-by-step solution

Disproportionation reactions are a special type of redox reactions. One of the reactants in a disproportionation reaction always contains an element that can exist in at least three oxidation states. The element of reacting species is in intermediate oxidation state and simultaneously gets oxidised and reduced. MnO42−,ClO2−,Cl2{MnO}_{4}^{2 -}, {ClO}_{2}^{-}, {Cl}_{2} and Mn3+{Mn}^{3 +} are having intermediate oxidation states.

Note: No option is correct in the actual question. One option is modified for its correctness.

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