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JEE Main 202127 JulyMorning Shift
Exam
JEE Main
Year
2021
Date
27 July
Shift
Morning Shift
Subject
Chemistry
Chapter
Redox Reactions

JEE Main 2021 · 27 July · Morning Shift · Chemistry · Redox Reactions

The oxidation states of ' P ' in H _ 4 P _ 2 O _ 7 , H _ 4 P _ 2 O...

The oxidation states of ′P′' P ' in H4P2O7,H4P2O5{H}_{4}{P}_{2}{O}_{7}, {H}_{4}{P}_{2}{O}_{5} and H4P2O6,{H}_{4}{P}_{2}{O}_{6}, respectively, are :

Options

  1. A7,57, 5 and 66
  2. B5,45, 4 and 33
  3. C5,35, 3 and 44
  4. D6,46, 4 and 55

Correct answer

C. 5,35, 3 and 44

Step-by-step solution

Oxidation state of PP in H4P2O7,H4P2O5{H}_{4}{P}_{2}{O}_{7}, {H}_{4}{P}_{2}{O}_{5} and H4P2O6{H}_{4}{P}_{2}{O}_{6} is 5,3 and 45, 3 \text{ and } 4 respectively

H4P2O7{H}_{4}{P}_{2}{O}_{7}
2x+4(+1)+7(−2)=02x + 4 ( + 1 ) + 7 ( - 2 ) = 0
x=+5x = + 5
H4P2¯O5{H}_{4}\mathop{{P}_{2}}_{¯}{O}_{5}
2x+4(+1)+5(−2)=02x + 4 ( + 1 ) + 5 ( - 2 ) = 0
x=+3x = + 3
H4P2¯O6{H}_{4}\mathop{{P}_{2}}_{¯}{O}_{6}
2x+4(+1)+6(−2)=02x + 4 ( + 1 ) + 6 ( - 2 ) = 0
x=+4x = + 4

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