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Olympiad workbook
Exam
Olympiad workbook
Subject
NSEC
Chapter
Coordination Compounds

Olympiad workbook · NSEC · Coordination Compounds

The observed effective magnetic moment of two octahedral complexes,...

The observed effective magnetic moment of two octahedral complexes, K4[Mn(CN)6].3H2O(X)\mathrm{K}_4\left[\mathrm{Mn}(\mathrm{CN})_6\right] .3 \mathrm{H}_2 \mathrm{O}(\mathrm{X}) and K4[Mn(SCN)6](Y)\mathrm{K}_4\left[\mathrm{Mn}(\mathrm{SCN})_6\right](\mathrm{Y}) are 2.18 BM and 6.06 BM , respectively. Which of the following is correct? I. XX is a low spin complex with two unpaired electrons II. YY is a high spin complex with 5 unpaired electrons III. XX is a high spin complex with two unpaired electrons IV. YY is a low spin complex with 5 unpaired electrons

Options

  1. AI and III
  2. BI,II\mathrm{I}, \mathrm{II}
  3. CI , II and IV
  4. DI, II and III

Correct answer

B. I,II\mathrm{I}, \mathrm{II}

Step-by-step solution

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