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Olympiad workbook
Exam
Olympiad workbook
Subject
NSEC
Chapter
Coordination Compounds

Olympiad workbook · NSEC · Coordination Compounds

The alkene ligand (π-C_2 R_4) is both a ' σ ' donor and a ' π '...

The alkene ligand (π−C2R4)\left(\pi-\mathrm{C}_2 \mathrm{R}_4\right) is both a ' σ\sigma ' donor and a ' π\pi ' acceptor, similar to the CO ligand in metal carbonyls, and exhibits synergic bonding with metals. Correct order of C−C\mathrm{C}-\mathrm{C} bond length in K[PtCl⁡3(π−C2R4)]\mathrm{K}\left[\operatorname{PtCl}_3 \left(\pi-\mathrm{C}_2 \mathrm{R}_4\right)\right] complexes in which R=H,F\mathrm{R}=\mathrm{H}, \mathrm{F} or CN is

Options

  1. AH>F>CN\mathrm{H}>\mathrm{F}>\mathrm{CN}
  2. BH>CN>F\mathrm{H}>\mathrm{CN}>\mathrm{F}
  3. CCN>F>H\mathrm{CN}>\mathrm{F}>\mathrm{H}
  4. DF>H>CN\mathrm{F}>\mathrm{H}>\mathrm{CN}

Correct answer

C. CN>F>H\mathrm{CN}>\mathrm{F}>\mathrm{H}

Step-by-step solution

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