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Olympiad workbook
Exam
Olympiad workbook
Subject
NSEC
Chapter
Coordination Compounds

Olympiad workbook · NSEC · Coordination Compounds

Using different reaction conditions nickel reacts with (p) Cl^ -...

Using different reaction conditions nickel reacts with (p) Cl−,(q)CN−,(r)CO\mathrm{Cl}^{-},(q) \mathrm{CN}^{-},(r) \mathrm{CO} and (s) small amount of Al. Choose incorrect statement.

Options

  1. A(p),(q)(\mathrm{p}),(\mathrm{q}), and (r)(\mathrm{r}) respectively can result in tetrahedral, octahedral and square planar geometries around nickel
  2. BLigand (p)(p) and (q)(q) leads to homoleptic complex formation wherein final electronic configuration shows maximum multiplicity in case of (p)
  3. CLigand (r) reacts only in reducing medium to form organometallic compound
  4. DIn case of(s) formation of spongy product with large surface drive reduction reaction of C=C\mathrm{C}=\mathrm{C} compounds

Correct answer

A. (p),(q)(\mathrm{p}),(\mathrm{q}), and (r)(\mathrm{r}) respectively can result in tetrahedral, octahedral and square planar geometries around nickel

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