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JEE Main 202116 MarchMorning Shift
Exam
JEE Main
Year
2021
Date
16 March
Shift
Morning Shift
Subject
Chemistry
Chapter
Redox Reactions

JEE Main 2021 · 16 March · Morning Shift · Chemistry · Redox Reactions

2 MnO _ 4 ^ - + bC _ 2 O _ 4 ^ 2 - + cH ^ + → xMn ^ 2 + + yCO _ 2 +...

2MnO4−+bC2O42−+cH+→xMn2++yCO2+zH2O2{MnO}_{4}^{-} + {bC}_{2}{O}_{4}^{2 -} + {cH}^{+} \to {xMn}^{2 +} + {yCO}_{2} + {zH}_{2}O
If the above equation is balanced with integer coefficients, the value of cc is _______ . (Round off to the Nearest Integer).

Correct answer

0

Step-by-step solution

Writing the half reaction

Reduction half reaction

MnO4−→Mn2+{MnO}_{4}^{-} \to {Mn}^{2 +}

balancing oxygen

MnO4−→Mn2++4H2O{MnO}_{4}^{-} \to {Mn}^{2 +} + 4{H}_{2}O

balancing Hydrogen

8H++MnO4−→Mn2++4H2O8{H}^{+} + {MnO}_{4}^{-} \to {Mn}^{2 +} + 4{H}_{2}O

balancing charge

5e−+8H++MnO4−→Mn2++4H2O5{e}^{-} + 8{H}^{+} + {MnO}_{4}^{-} \to {Mn}^{2 +} + 4{H}_{2}O

Oxidation half

C2O42−→CO2{C}_{2}{O}_{4}^{2 -} \to {CO}_{2}
Balancing carbon

C2O42−→2CO2{C}_{2}{O}_{4}^{2 -} \to 2{CO}_{2}

Balancing charge

C2O42−→2CO2+2e−{C}_{2}{O}_{4}^{2 -} \to 2{CO}_{2} + 2{e}^{-}

Net equation

16H++2MnO4−+5C2O42−→10CO2+2Mn2++8H2O16{H}^{+} + 2{MnO}_{4}^{-} + 5{C}_{2}{O}_{4}^{2 -} \to 10{CO}_{2} + 2{Mn}^{2 +} + 8{H}_{2}O

So c=16c = 16

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