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Exam
Olympiad workbook
Subject
NSEC
Chapter
Ionic Equilibrium

Olympiad workbook · NSEC · Ionic Equilibrium

At 25^ ^ ^ CK_ a of HPO_4 ^ 2- and HSO_3 ^ - are 4.8 × 10^ -13 and...

At 25∘CKa25^{{}^{{}^{\circ}}} \mathrm{CK}_{\mathrm{a}} of HPO42−\mathrm{HPO}_4{ }^{2-} and HSO3−\mathrm{HSO}_3{ }^{-}are 4.8×10−134.8 \times 10^{-13} and 6.3×10−86.3 \times 10^{-8} respectively. Which of the following is correct?

Options

  1. AHPO42−\mathrm{HPO}_4{ }^{2-} is a stronger acid than HSO3−\mathrm{HSO}_3{ }^{-}and PO43−\mathrm{PO}_4{ }^{3-} is a weaker base than SO32−\mathrm{SO}_3{ }^{2-}
  2. BHPO42−\mathrm{HPO}_4{ }^{2-} is a weaker acid than HSO3−\mathrm{HSO}_3{ }^{-}and PO43−\mathrm{PO}_4{ }^{3-} is a weaker base than SO32−\mathrm{SO}_3{ }^{2-}
  3. CHPO42−\mathrm{HPO}_4{ }^{2-} is a weaker acid than HSO3−\mathrm{HSO}_3{ }^{-}and PO43−\mathrm{PO}_4{ }^{3-} is a stronger base than SO32−\mathrm{SO}_3{ }^{2-}
  4. DHPO42−\mathrm{HPO}_4{ }^{2-} is a stronger acid than HSO3−\mathrm{HSO}_3{ }^{-}and PO43−\mathrm{PO}_4{ }^{3-} is a stronger base than SO32−\mathrm{SO}_3{ }^{2-}

Correct answer

C. HPO42−\mathrm{HPO}_4{ }^{2-} is a weaker acid than HSO3−\mathrm{HSO}_3{ }^{-}and PO43−\mathrm{PO}_4{ }^{3-} is a stronger base than SO32−\mathrm{SO}_3{ }^{2-}

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