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JEE Main 201912 JanuaryMorning Shift
Exam
JEE Main
Year
2019
Date
12 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Redox Reactions

JEE Main 2019 · 12 January · Morning Shift · Chemistry · Redox Reactions

50mL of 0 .5 M oxalic acid is needed to neutralize 25mL of sodium...

50mL50mL of 0.5M0 .5 M oxalic acid is needed to neutralize 25mL25mL of sodium hydroxide solution. What is the amount of NaOHNaOH in 50mL50mL of the given sodium hydroxide solution?

Options

  1. A2g2g
  2. B4g\text{4}g
  3. C1g1g
  4. D8g8g

Correct answer

B. 4g\text{4}g

Step-by-step solution

millimoles of oxalic acid =50×0.5= 50 \times 0.5

milli equivalent of oxalic acid =50×0.5×2= 50 \times 0.5 \times 2

millimoles of NaOH=25×M=NaOH = 25 \times M = milli equivalent of NaOHNaOH

∴50×0.5×2=25×M∴ 50 \times 0 .5 \times 2 = 25 \times M

⇒M=2⇒ M = 2

M=2M = 2 so, 1000ml1000\text{ml} NaOHNaOH solution contains

=2mol ofNaOH= 2\text{mol of}NaOH

=2×40=80gNaOH= 2 \times 40 = 80\text{g}NaOH

∴50mlNaOH∴ 50\text{ml}NaOH solution contains =801000×50=4g= \dfrac{80}{1000} \times 50 = 4\text{g}
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