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Exam
Olympiad workbook
Subject
NSEC
Chapter
Chemical Kinetics

Olympiad workbook · NSEC · Chemical Kinetics

For an elementary rearrangement reaction A leftharpoons P , the...

For an elementary rearrangement reaction A⇌P\mathrm{A} \rightleftharpoons \mathrm{P}, the following data were recorded at 303 K , when [P]0=0[\mathrm{P}]_0=0 :
Set No. [A]0/molL−1[A]_0 / mol\mathrm{L}^{-1} Rate of conversion of A/molL−1min⁡−1A/ mol\mathrm{L}^{-1}\min ^{-1}
1 0.3400.340 0.1000.100
2 0.1700.170 0.0500.050
3 0.0850.085 0.0250.025
If the equilibrium constant of the reaction is 1.12 at 303 K , the rate constant for the reaction P→A\mathrm{P} \rightarrow \mathrm{A} is

Options

  1. A0.263 min−10.263 \mathrm{~min}^{-1}
  2. B0.294 min−10.294 \mathrm{~min}^{-1}
  3. C0.526 min−10.526 \mathrm{~min}^{-1}
  4. D0.588 min−10.588 \mathrm{~min}^{-1}

Correct answer

A. 0.263 min−10.263 \mathrm{~min}^{-1}

Step-by-step solution

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