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Olympiad workbook
Exam
Olympiad workbook
Subject
NSEC
Chapter
Chemical Kinetics

Olympiad workbook · NSEC · Chemical Kinetics

For the reaction 5 Br^ - (aq)+BrO_3^ - (aq)+6 H^ + (aq) arrow 3...

For the reaction 5Br−(aq)+BrO3−(aq)+6H+(aq)→3Br2(aq)+3H2O(l)5 \mathrm{Br}^{-}(\mathrm{aq})+\mathrm{BrO}_3^{-}(\mathrm{aq})+6 \mathrm{H}^{+}(\mathrm{aq}) \rightarrow 3 \mathrm{Br}_2(\mathrm{aq})+3 \mathrm{H}_2 \mathrm{O}(\mathrm{l}) the rate expression was found to be −d-\mathrm{d}\left[\mathrm{BrO}}_{3}{ }^{-}\right] / dt=k\mathrm{dt}=\mathrm{k} \left[\mathrm{Br}^{-}\right] \left[\mathrm{H}^{+}\right]^2 \left[\mathrm{BrO}}_{3}{ }^{-}\right]Whichofthefollowingstatement/sis/arecorrect?I.Doublingtheinitialconcentrationofallthereactantswillincreasethereactionratebyafactorof8II.UnitofrateconstantofthereactioninabuffersolutionisWhich of the following statement/s is /are correct? I. Doubling the initial concentration of all the reactants will increase the reaction rate by a factor of 8 II. Unit of rate constant of the reaction in a buffer solution is\min ^{-1}III. Doubling the concentration of all the reactants at the same time will increase the reaction rate by a factor of 16 IV. rate of conversion of \mathrm{BrO}}_{3}^{-}and rate of formation of \mathrm{Br}^{-}are the same

Options

  1. AI and II
  2. BII and III
  3. CII and IV
  4. DIII only

Correct answer

D. III only

Step-by-step solution

No Solution (Deleted)
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