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JEE Main202228 Jul 2022Morning ShiftChemistrys Block ElementsActual

Which of the following statements is incorrect?

Options

  1. ALow solubility of LiF in water is due to its small hydration enthalpy.
  2. BKO 2 is paramagnetic.
  3. CSolution of sodium in liquid ammonia is conducting in nature.
  4. DSodium metal has higher density than potassium metal

Correct answer

A. Low solubility of LiF in water is due to its small hydration enthalpy.

Step-by-step solution

Due to the small size of Li + ion and F - ions, the lattice energy of LiF is very high. LiF is covalent in nature. Therefore, LiF is insoluble in water. KO 2 has 1 unpaired electron in π ⋆ 2 p   Molecular   orbital of O 2 - . Therefore, it is Paramagnetic. Lithium has lesser atomic weight than sodium. So, lithium has lesser density than sodium. But in the case of ' K ' and ' Na ', d -orbitals present in Potassium, which increases the volume of ' K '. Solution of sodium i

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