JEE Main202227 Jul 2022Evening ShiftChemistrys Block ElementsActual
An element A of group 1 shows similarity to an element B belonging to group 2 . If A has maximum hydration enthalpy in group 1 then B is
Options
- AMg
- BBe
- CCa
- DSr
Correct answer
A. Mg
Step-by-step solution
Hydration enthalpy is inversely related to the size of the ion. Li + has maximum hydration enthalpy in group 1 due to its small size. Lithium shows diagonal relationship to magnesium. The similarity between lithium and magnesium is particularly striking and arises because of their similar sizes : atomic radii, Li = 152 pm, Mg = 160 pm; ionic radii : Li + = 76 pm, Mg 2+ = 72 pm. The main points of similarity are (I)Both lithium and magnesium are harder and lighter (ii) Lithium and magnesium react slowly with water.