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JEE Main 202226 JulyEvening Shift
Exam
JEE Main
Year
2022
Date
26 July
Shift
Evening Shift
Subject
Chemistry
Chapter
s Block Elements

JEE Main 2022 · 26 July · Evening Shift · Chemistry · s Block Elements

Given below are two statements: one is labelled as Assertion A and...

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason RR. Assertion AA : LiFLiF is sparingly soluble in water. Reason RR : The ionic radius of Li+{Li}^{+} ion is smallest among its group members, hence has least hydration enthalpy.

In the light of the above statements, choose the most appropriate answer from the options given below.

Options

  1. ABoth AA and RR are true and RR is the correct explanation of AA
  2. BBoth AA and RR are true but RR is NOT the correct explanation of AA
  3. CAA is true but RR is false
  4. DAA is false but RR is true

Correct answer

C. AA is true but RR is false

Step-by-step solution

The low solubility of LiFLiF in water is due to its high lattice enthalpy.

The hydration enthalpies of alkali metal ions in aqueous solution decreases with increase in ionic sizes.

Li+>Na+>K+>Rb+>Cs+{Li}^{+} > {Na}^{+} > {K}^{+} > {Rb}^{+} > {Cs}^{+}

Li+{Li}^{+} has maximum degree of hydration and for this reason lithium salts are mostly hydrated, e.g., LiCl.2H2OLiCl . 2{H}_{2}O

Hence, A is true and R is false.

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