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JEE Main 20264 AprilMorning Shift
Exam
JEE Main
Year
2026
Date
4 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Solutions

JEE Main 2026 · 4 April · Morning Shift · Chemistry · Solutions

A non-volatile, non-electrolyte solid solute when dissolved in 40 g...

A non-volatile, non-electrolyte solid solute when dissolved in 4040 g of a solvent, the vapour pressure of the solvent decreased from 760760 mm Hg to 750750 mm Hg. If the same solution boils at 320320 K, then the number of moles of the solvent present in the solution is _____. (Nearest integer)
[Given: boiling point of the pure solvent =319.5= 319.5 K, KbK_b of the solvent =0.3= 0.3 K kg mol−1^{-1}]

Correct answer

0

Step-by-step solution

From the relative lowering of vapour pressure, we have:

P0−PsPs=nBnA\dfrac{P^0 - P_s}{P_s} = \dfrac{n_B}{n_A}

where nBn_B is the number of moles of solute and nAn_A is the number of moles of solvent.

Substituting the given values:

760−750750=nBnA\dfrac{760 - 750}{750} = \dfrac{n_B}{n_A}

10750=nBnA⇒nA=75nB\dfrac{10}{750} = \dfrac{n_B}{n_A} \Rightarrow n_A = 75 n_B

The elevation in boiling point is given by:

ΔTb=Tb−Tb0=320−319.5=0.5\Delta T_b = T_b - T_b^0 = 320 - 319.5 = 0.5 K

We also know that ΔTb=Kb×m\Delta T_b = K_b \times m, where mm is the molality of the solution.

m=nBMass of solvent in kg=nB0.04m = \dfrac{n_B}{\text{Mass of solvent in kg}} = \dfrac{n_B}{0.04}

Substituting the values into the elevation in boiling point equation:

0.5=0.3×nB0.040.5 = 0.3 \times \dfrac{n_B}{0.04}

nB=0.5×0.040.3=0.020.3=115n_B = \dfrac{0.5 \times 0.04}{0.3} = \dfrac{0.02}{0.3} = \dfrac{1}{15} mol

Now, substituting nBn_B back to find the number of moles of the solvent nAn_A:

nA=75×115=5n_A = 75 \times \dfrac{1}{15} = 5 mol

Answer: 55
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