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JEE Main 20231 FebruaryEvening Shift
Exam
JEE Main
Year
2023
Date
1 February
Shift
Evening Shift
Subject
Chemistry
Chapter
Solutions

JEE Main 2023 · 1 February · Evening Shift · Chemistry · Solutions

20 % of acetic acid is dissociated when its 5g is added to 500mL of...

2020 % of acetic acid is dissociated when its 5g5g is added to 500mL500mL of water. The depression in freezing point of such water is _____ \times {10}^{- 3} C ∘. Atomic mass of C,HC, H and OO are 12,112, 1 and 1616 a.m.u. respectively.

[Given : Molal depression constant and density of water are 1.86Kkgmol−11 . 86Kkg{mol}^{- 1} and 1gcm−31g{cm}^{- 3} respectively.

Correct answer

372

Step-by-step solution

Van't Hoff factor (i) for dissociation of acetic acid can be written as follows,

i=1+(n−1)αi = 1 + ( n - 1 ) \alpha

n=n =Number of ions

α=\alpha =Degree of dissociation

(i=1+0.2(2−1)=1.2( i = 1 + 0 . 2 ( 2 - 1 ) = 1 . 2

ΔTf=iKfmΔTf=DepressioninfreezingpointKf=Molardepressionconstantm=molality{\Delta T}_{f} = {iK}_{f}m{\Delta T}_{f} = Depressioninfreezingpoint{K}_{f} = Molardepressionconstantm = molality

ΔTf=1.2×1.86×5×100060×500{\Delta T}_{f} = 1 . 2 \times 1 . 86 \times \dfrac{5 \times 1000}{60 \times 500}

ΔTf=0.372{\Delta T}_{f} = 0 . 372

ΔTf=372×10−3\Delta{T}_{f} = 372 \times {10}^{- 3}

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