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JEE Main 202229 JuneMorning Shift
Exam
JEE Main
Year
2022
Date
29 June
Shift
Morning Shift
Subject
Chemistry
Chapter
Solutions

JEE Main 2022 · 29 June · Morning Shift · Chemistry · Solutions

1 . 2mL of acetic acid is dissolved in water to make 2 . 0L of...

1.2mL1 . 2mL of acetic acid is dissolved in water to make 2.0L2 . 0L of solution. The depression in freezing point observed for this strength of acid is 0.0198°C0 . 0198 ° C. The percentage of dissociation of the acid is (Nearest integer) [Given : Density of acetic acid is 1.02gmL−11 . 02g{mL}^{- 1} Molar mass of acetic acid is 60gmol−160g{mol}^{- 1}
Kf(H2O)=1.85Kkgmol−1{K}_{f}\left({H}_{2}O\right) = 1 . 85Kkg{mol}^{- 1}]

Correct answer

0

Step-by-step solution

M=d×V=1.02×1.2=1.224gmM = d \times V = 1 . 02 \times 1 . 2 = 1 . 224gm

Moles of acetic acid =0.0204= 0 . 0204 moles in 2L2L

So molality =0.0102mol/kg= 0 . 0102mol / kg

Now ΔTf=i×Kf×m{\Delta T}_{f} = i \times {K}_{f} \times m

i=1+αi = 1 + \alpha for acetic acid

0.0198=(1+α)×1.85×0.01020 . 0198 = \left(1 + \alpha\right) \times 1 . 85 \times 0 . 0102

α=0.04928\alpha = 0 . 04928

≅5≅ 5 %

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