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JEE Main 202125 FebruaryEvening Shift
Exam
JEE Main
Year
2021
Date
25 February
Shift
Evening Shift
Subject
Chemistry
Chapter
Solutions

JEE Main 2021 · 25 February · Evening Shift · Chemistry · Solutions

If a compound AB dissociates to the extent of 75 % in an aqueous...

If a compound ABAB dissociates to the extent of 7575 % in an aqueous solution, the molality of the solution which shows a 2.5K2 . 5K rise in the boiling point of the solution is ___ molal. (Rounded-off to the nearest integer) [Kb=0.52Kkgmol−1]\left[{K}_{b} = 0 . 52Kkg{mol}^{- 1}\right].

Correct answer

0

Step-by-step solution

α=0.75,n=2\alpha = 0 . 75, n = 2

i=1−α+nα=1−0.75+2×0.75=1.75i = 1 - \alpha + n\alpha = 1 - 0 . 75 + 2 \times 0 . 75 = 1 . 75

ΔTb=ikbm\Delta{T}_{b} = {ik}_{b}m

or 2.5=1.75×0.52×m2 . 5 = 1 . 75 \times 0 . 52 \times m

or, m=2.51.75×0.52=2.74m = \dfrac{2 . 5}{1 . 75 \times 0 . 52} = 2 . 74

∴∴ nearest integer answer will be 33

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