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JEE Main 20169 AprilOnline
Exam
JEE Main
Year
2016
Date
9 April
Mode
Online
Subject
Chemistry
Chapter
Solutions

JEE Main 2016 · 9 April · Online · Chemistry · Solutions

The solubility of N _ 2 in water at 300K and 500torr partial...

The solubility of N2{N}_{2} in water at 300K\text{300}\text{K} and 500torr\text{500}\text{torr} partial pressure is~0.01gL−1.0 .01 gL^{- 1} . The solubility (in g L−1{\text{g L}}^{- \text{1}} ) at 750torr\text{750}\text{torr} partial pressure is:

Options

  1. A0.00750.0075
  2. B0.0050.005
  3. C0.020 . 02
  4. D0.0150.015

Correct answer

D. 0.0150.015

Step-by-step solution

p=KHXp = {K}_{H}X
where p→p \to Partial pressure of gas
X2→{X}_{2} \to Mole fraction of gas in solution
KH={K}_{H} = Henry's law constant
So, p∝p ∝ solubility
p1p2=s1s2⇒5000.01=750x\dfrac{{p}_{1}}{{p}_{2}} = \dfrac{{s}_{1}}{{s}_{2}} ⇒ \dfrac{500}{0 . 01} = \dfrac{750}{x}
∴x=0.015g/L∴ x = 0 . 015g / L
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