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JEE Main 20265 AprilMorning Shift
Exam
JEE Main
Year
2026
Date
5 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Structure of Atom

JEE Main 2026 · 5 April · Morning Shift · Chemistry · Structure of Atom

Arrange the following atomic orbitals of multi electron atoms in...

Arrange the following atomic orbitals of multi electron atoms in order of increasing energy.
A. n=3,l=2,m=+1n = 3, l = 2, m = +1
B. n=4,l=0,m=0n = 4, l = 0, m = 0
C. n=6,l=1,m=0n = 6, l = 1, m = 0
D. n=5,l=1,m=+1n = 5, l = 1, m = +1
E. n=2,l=1,m=+1n = 2, l = 1, m = +1
Choose the correct answer from the options given below:

Options

  1. AC<D<B<A<EC < D < B < A < E
  2. BB<A<E<C<DB < A < E < C < D
  3. CE<C<D<B<AE < C < D < B < A
  4. DE<B<A<D<CE < B < A < D < C

Correct answer

D. E<B<A<D<CE < B < A < D < C

Step-by-step solution

The energy of an atomic orbital in a multi-electron atom is determined by the (n+l)(n + l) rule. Orbitals with a lower value of (n+l)(n + l) have lower energy. If two orbitals have the same (n+l)(n + l) value, the one with the lower nn value has lower energy.

Calculating the (n+l)(n + l) value for each given orbital:
A. n=3,l=2⇒n+l=5n = 3, l = 2 \Rightarrow n + l = 5
B. n=4,l=0⇒n+l=4n = 4, l = 0 \Rightarrow n + l = 4
C. n=6,l=1⇒n+l=7n = 6, l = 1 \Rightarrow n + l = 7
D. n=5,l=1⇒n+l=6n = 5, l = 1 \Rightarrow n + l = 6
E. n=2,l=1⇒n+l=3n = 2, l = 1 \Rightarrow n + l = 3

Arranging the orbitals in increasing order of their (n+l)(n + l) values, we get:
3<4<5<6<73 < 4 < 5 < 6 < 7

This corresponds to the order:
E<B<A<D<CE < B < A < D < C

Answer: E<B<A<D<CE < B < A < D < C
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