AP EAMCET202318 May 2023Morning ShiftChemistryCoordination CompoundsActual
The spin only magnetic moment of [ MnBr ₄ ]^ x - is 5.9 BM . The geometry of the complex and x respectively are
Options
- Atetrahedral, 1
- Bsquare planar, 1
- Csquare planar, 2
- Dtetrahedral, 2
Correct answer
D. tetrahedral, 2
Step-by-step solution
_ s = n ( n +2) =5.9 B. M. ^2= n ( n +2)=34.81 n =5 Thus, Mn will have five unpaired electrons so Mn will be in +2 state with Br ⁻ being weak- field ligands. Thus, x=2 for [ Mn Br ₄ ]²⁻