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AP EAMCET202318 May 2023Morning ShiftChemistryCoordination CompoundsActual

The spin only magnetic moment of [ MnBr ₄ ]^ x - is 5.9 BM . The geometry of the complex and x respectively are

Options

  1. Atetrahedral, 1
  2. Bsquare planar, 1
  3. Csquare planar, 2
  4. Dtetrahedral, 2

Correct answer

D. tetrahedral, 2

Step-by-step solution

_ s = n ( n +2) =5.9 B. M. ^2= n ( n +2)=34.81 n =5 Thus, Mn will have five unpaired electrons so Mn will be in +2 state with Br ⁻ being weak- field ligands. Thus, x=2 for [ Mn Br ₄ ]²⁻

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