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AP EAMCET201824 Apr 2018Morning ShiftChemistryCoordination CompoundsActual

The green coloured complex ion of nickel in its aqueous solution is

Options

  1. A[ Ni ( en )₃ ]²⁺
  2. B[ Ni ( H ₂ O )₂( en )₂ ]²⁺
  3. C[ Ni ( H ₂ O )₄( en ) ]²⁺
  4. D[ Ni ( H ₂ O )₆ ]²⁺

Correct answer

D. [ Ni ( H ₂ O )₆ ]²⁺

Step-by-step solution

In complex [ Ni ( H ₂ O )₆ ]²⁺ the strong ligand is absent. Thus, electrons do not go for pairing and two unpaired e⁻ are present in Ni ²⁺ complex. Hence, is a coloured complex.

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