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AP EAMCET2012ChemistryCoordination Compounds

A coordinate complex contains Co ³⁺, Cl ⁻ and NH ₃ . When dissolved in water, one mole of this complex gave a total of 3 moles of ions. The complex is

Options

  1. A[ Co ( NH ₃ )₆ ] Cl ₃
  2. B[ Co ( NH ₃ )₅ Cl ] Cl ₂
  3. C[ Co ( NH ₃ )₄ Cl ₂ ] Cl
  4. D[ Co ( NH ₃ )₃ Cl ₃ ]

Correct answer

B. [ Co ( NH ₃ )₅ Cl ] Cl ₂

Step-by-step solution

When the complex dissolved in water, it gives three ions, which shows that two Cl ⁻ ions are present outside the coordination sphere. The formula of the complex is aligned & [ Co ( NH ₃ )₅ Cl ] Cl ₂ & [ Co ( NH ₃ )₅ Cl ] Cl ₂ Water [ Co ( NH ₃ )₅ Cl ²⁺+2 Cl ⁻ . _ 3 ion aligned

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