AP EAMCET202315 May 2023Morning ShiftChemistryd and f Block ElementsActual
From the list given below, the number of lanthanides which exhibit +4 state in their oxides is Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy
Options
- A5
- B4
- C6
- D2
Correct answer
B. 4
Step-by-step solution
Pr , Nd , Tb and Dy exhibit +4 state in their oxides as they acquire configurations closer to stable 4 f ^ and 4 f ^7 configurations. aligned & Pr ⁴⁺=[ Xe ] 4 f ^1, Nd ⁴⁺=[ Xe ] 4 f ^2, Pm ⁴⁺=[ Xe ] 4 f ^3 & Sm ⁴⁺=[ Xe ] 4 f ^4, Eu ⁴⁺=[ Xe ] 4 f ^5, Gd ⁴⁺=[ Xe ] 4 f ^6, & ~Tb ⁴⁺=[ Xe ] 4 f ^7, Dy ⁴⁺=[ Xe ] 4 f ^6 . aligned