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JIPMER 2010
Exam
JIPMER
Year
2010
Subject
Chemistry
Chapter
Amines

JIPMER 2010 · Chemistry · Amines

Which of the organic compounds will give red colour in Lassaigne...

Which of the organic compounds will give red colour in Lassaigne test?Which of the organic compounds will give red colour in Lassaigne test?Which of the organic compounds will give red colour in Lassaigne test?

Options

  1. AC6H5NH2\mathrm{C}_6 \mathrm{H}_5 \mathrm{NH}_2
  2. BWhich of the following 0. 1M aqueous solution will have lowest freezing point?
  3. CWhich of the following 0. 1M aqueous solution will have lowest freezing point?
  4. DNone of these

Correct answer

B. Which of the following 0. 1M aqueous solution will have lowest freezing point?

Step-by-step solution

If both nitrogen and sulphur are present in a organic compound, they will give red blood colour with Lassaigne test due to the formation of ferric thiocyanate. Na+C+S+N→ΔNaSCN sodium. thiocyanate Fe3++3NaSCN⟶Fe(SCN)3+3Na+ferric thiocyanate  (blood red colouration) \begin{aligned} & \mathrm{Na}+\mathrm{C}+\mathrm{S}+\mathrm{N} \xrightarrow{\Delta} \quad \mathrm{NaSCN} \\ & \text{ sodium. thiocyanate } \\ & \mathrm{Fe}^{3+}+3 \mathrm{NaSCN} \longrightarrow \mathrm{Fe}(\mathrm{SCN})_3+3 \mathrm{Na}^{+} \\ & \text{ferric thiocyanate } \\ & \text{ (blood red colouration) } \\ & \end{aligned}
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