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JIPMER 2016
Exam
JIPMER
Year
2016
Subject
Chemistry
Chapter
Amines

JIPMER 2016 · Chemistry · Amines

Which of the following is an example of carbylamine reaction?

Which of the following is an example of carbylamine reaction?Which of the following is an example of carbylamine reaction?Which of the following is an example of carbylamine reaction?Which of the following is an example of carbylamine reaction?Which of the following is an example of carbylamine reaction?Which of the following is an example of carbylamine reaction?Which of the following is an example of carbylamine reaction?

Options

  1. AWhat type of reaction is involved when phthalimide reacts with an alkyl halide in the Gabriel synthesis?
  2. BWhat type of reaction is involved when phthalimide reacts with an alkyl halide in the Gabriel synthesis?
  3. CPh−NH2+CHCl3+3KOH( alc. )→ΔPh−NC+3KCl+3H2O\begin{aligned} \mathrm{Ph}-\mathrm{NH}_2+\mathrm{CHCl}_3+3 \mathrm{KOH}(\text{ alc. }) \xrightarrow{\Delta} \\ \mathrm{Ph}-\mathrm{NC}+3 \mathrm{KCl}+3 \mathrm{H}_2 \mathrm{O}\end{aligned}
  4. DPh2−NH+HONO⟶Ph2−N−\mathrm{Ph}_2-\mathrm{NH}+\mathrm{HONO} \longrightarrow \mathrm{Ph}_2-\mathrm{N}-\mathrm{N}=\mathrm{O}+H2O+\mathrm{H}_2 \mathrm{O}

Correct answer

C. Ph−NH2+CHCl3+3KOH( alc. )→ΔPh−NC+3KCl+3H2O\begin{aligned} \mathrm{Ph}-\mathrm{NH}_2+\mathrm{CHCl}_3+3 \mathrm{KOH}(\text{ alc. }) \xrightarrow{\Delta} \\ \mathrm{Ph}-\mathrm{NC}+3 \mathrm{KCl}+3 \mathrm{H}_2 \mathrm{O}\end{aligned}

Step-by-step solution

(1)Which of the following is an example of carbylamine reaction? (2)Which of the following is an example of carbylamine reaction? (3)Which of the following is an example of carbylamine reaction? (4)Which of the following is an example of carbylamine reaction?
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