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JIPMER2015ChemistryCarboxylic Acid Derivatives

When a mixture of 1-hexanol and hexanoic acid in diethyl ether is shaken with an aqueous NaHCO ₃ solution, then which of the following is right distribution?

Options

  1. AIn ether: hexanoic acid; In NaHCO ₃ : 1-hexanol
  2. BIn ether: 1-hexanol ; In NaHCO ₃ : sodium hexanoate
  3. CIn ether: sodium hexaonate ; In NaHCO ₃ : 1hexanol
  4. DIn ether: 1-hexanol ; In NaHCO ₃ : hexanoic acid

Correct answer

B. In ether: 1-hexanol ; In NaHCO ₃ : sodium hexanoate

Step-by-step solution

Hexanoic acid is soluble in ether whereas alcohol is not soluble in NaHCO ₃ solution.

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