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JIPMER 2017
Exam
JIPMER
Year
2017
Subject
Chemistry
Chapter
Chemical Kinetics

JIPMER 2017 · Chemistry · Chemical Kinetics

For the chemical reaction, 2 O_3 leftharpoons 3 O_2 The reaction...

For the chemical reaction, 2O3⇌32 \mathrm{O}_3 \rightleftharpoons 3O2\mathrm{O}_2ThereactionproceedasfollowsThe reaction proceed as follows\begin{gathered}\mathrm{O}_3 \rightleftharpoons \mathrm{O}_2+\mathrm{O} \text{ (fast) } \\ \mathrm{O}+\mathrm{O}_3 \longrightarrow 2 \mathrm{O}_2 \text{ (slow) }\end{gathered}$ The rate law expression will be

Options

  1. Ar=k′[O3]2r=k^{\prime}\left[\mathrm{O}_3\right]^2
  2. Br=k′r=k^{\prime}\left[\mathrm{O}_3\right]^2[O2]−1\left[\mathrm{O}_2\right]^{-1}
  3. Cr=k′[O3][O2]r=k^{\prime}\left[\mathrm{O}_3\right]\left[\mathrm{O}_2\right]
  4. DUnpredictable

Correct answer

B. r=k′r=k^{\prime}\left[\mathrm{O}_3\right]^2[O2]−1\left[\mathrm{O}_2\right]^{-1}

Step-by-step solution

As slowest step is the rate determining step. Hence, from slow reaction, r=K[O]r=K[\mathrm{O}]\left[\mathrm{O}_3\right]...(i)Fromfastreaction,From fast reaction,K_C=\frac{\left[\mathrm{O}_2\right][\mathrm{O}]}{\left[\mathrm{O}_3\right]} [O]=KC⋅[O3][O2], i.e. r=KC[O3][O2]⋅[O3]\begin{aligned} {[\mathrm{O}] } & =\frac{K_C \cdot\left[\mathrm{O}_3\right]}{\left[\mathrm{O}_2\right]}, \text{ i.e. } \\ r & =\frac{K_C\left[\mathrm{O}_3\right]}{\left[\mathrm{O}_2\right]} \cdot\left[\mathrm{O}_3\right]\end{aligned} \Rightarrow K_C \cdot[O3]2[O2]−1∴\left[\mathrm{O}_3\right]^2\left[\mathrm{O}_2\right]^{-1}\therefore Rate $(r)=K^{\prime}\left[\mathrm{O}_3\right]^2 \cdot\left[\mathrm{O}_2\right]^{-1}\left(K^{\prime}=K_C \cdot K\right)
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