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JIPMER 2015
Exam
JIPMER
Year
2015
Subject
Chemistry
Chapter
Solutions

JIPMER 2015 · Chemistry · Solutions

For preparing 3.00 L of 1 M NaOH by mixing portions of two stock...

For preparing 3.00 L of 1 M NaOH by mixing portions of two stock solutions ( AA and BB ) of 2.50 M NaOH and 0.40 M NaOH respectively. Find out the amount of BB stock solution (in L ) added.

Options

  1. A8.57L8.57 L
  2. B2.14L2.14 L
  3. C1.28L1.28 L
  4. D7.51L7.51 L

Correct answer

B. 2.14L2.14 L

Step-by-step solution

Moles needed =(3.00 L)(1.00M)=3 mol=(3.00 \mathrm{~L})(1.00 \mathrm{M})=3 \mathrm{~mol}. Suppose that x Lx \mathrm{~L} of 2.50 M NaOH added, then (3−x)L(3-x) \mathrm{L} of 0.40 M NaOH added. The number of moles of solute from the more concentrated solution is 2.50 , that become less concentrated solution is (0.40)(3.00−x)(0.40)(3.00-x). The total number of moles is 3.00 . (2.50x)+(0.40)(3.00−x)=3.00(2.50 x)+(0.40)(3.00-x)=3.00 or 2.10x+1.2=32.10 x+1.2=3 Or 2.10x=1.82.10 x=1.8 or x=0.857 Lx=0.857 \mathrm{~L} of 2.50 M NaOH ∴(3−0.857)=2.14\therefore \quad(3-0.857)=2.14 L of 0.40 M NaOH
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