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JIPMER 2019
Exam
JIPMER
Year
2019
Subject
Chemistry
Chapter
States of Matter

JIPMER 2019 · Chemistry · States of Matter

Moles of N_2=0.4 and moles of O_2=0.1 find p_ N_2 (Partial...

Moles of N2=0.4\mathrm{N}_2=0.4 and moles of O2=0.1\mathrm{O}_2=0.1 find pN2\mathrm{p}_{\mathrm{N}_2} (Partial pressure) N2=\mathrm{N}_2= ?at atmospherim pressure

Options

  1. A0.2 atm
  2. B0.8 atm
  3. C0.6 atm
  4. D0.4 atm

Correct answer

B. 0.8 atm

Step-by-step solution

Key Idea According to Raoult's law, "at a given temperature, for a solution of volatile liquids, the partial vapour pressure of each component of the solution is direcently proportional to its mole fraction present in solution. According to Raoult's law, pA=xApT=nAnA+nBpT\mathrm{p}_{\mathrm{A}}=\mathrm{x}_{\mathrm{A}} \mathrm{p}_{\mathrm{T}}=\frac{\mathrm{n}_{\mathrm{A}}}{\mathrm{n}_{\mathrm{A}}+\mathrm{n}_{\mathrm{B}}} \mathrm{p}_{\mathrm{T}} where, PA=\mathrm{P}_{\mathrm{A}}= partial pressure pT=\mathrm{p}_{\mathrm{T}}= total pressure nA\mathrm{n}_{\mathrm{A}} and nB=\mathrm{n}_{\mathrm{B}}= moles Given, nN2=0.4,nO2=0.1,pT=1 atm{ }^{\mathrm{n}} \mathrm{N}_2=0.4,{ }^{\mathrm{n}} \mathrm{O}_2=0.1, \mathrm{p}_{\mathrm{T}}=1 \mathrm{~atm}∴PN2=nN2nN2+nO2PT=0.40.4+0.1×1 atm=0.40.5=0.8 atm\begin{aligned} \therefore \quad \mathrm{P}_{\mathrm{N}_2} & =\frac{\mathrm{n}_{\mathrm{N}_2}}{\mathrm{n}_{\mathrm{N}_2}+\mathrm{n}_{\mathrm{O}_2}} \mathrm{P}_{\mathrm{T}}=\frac{0.4}{0.4+0.1} \times 1 \mathrm{~atm} \\ & =\frac{0.4}{0.5}=0.8 \mathrm{~atm} \end{aligned}$$
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