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States of Matter — NEET UG Chemistry PYQs

414 previous year questions from States of Matter with answers and solutions. Numbered list, year tags, and one-tap solutions — built for serious JEE / NEET practice.

414 questionsChemistrySolutions on every page
1

A steel cylinder of 8 litres capacity contain hydrogen gas at 12 atm pressure, At same temperature, how many cycle tubes of 4 litre capacity at 2 atmphere can be filled up with thi

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2

The volume occupied by a given mass of gas at 298 K is 35 mL at 1 atmospheric pressure. Calculate the volume of the gas if pressure is decreased to 0.75 atmosphere at constant temp

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3

A bubble of air is underwater at temperature 15 ^ C and the pressure 1.5 bar . If the bubble rises to the surface where the temperature is 25 ^ C and the pressure is 1.0 bar , what

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4

Calculate the work done terms of dm ^3 bar when 200 ml of ethylene gas and 150 ml of HCl gas were allowed to react at 1 bar pressure.

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5

A force of 450 N acts on a surface area of 15 cm ^2 . Find the pressure exerted.

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6

Calculate the pressure in atm of 48 g oxygen gas in a 2 dm ^3 container at 27 ^ C . [ R = 0.0821 atm dm ^3 K ⁻¹ mol ⁻¹ ]

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7

Identify false statement about real gas from following .

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8

Find the number of molecules in 0.25 m ^3 of the gas at a pressure 2.0 10^2 kPa and a temperature 300 K . [R = 8.314 J K ⁻¹ mol ⁻¹]

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9

Which of the following relations is correct regarding rate of diffusion of a gas?

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10

The density of a gas at 27^ C and 1 atm pressure is 2.6 g/dm ^3 . What is molar mass of gas? [R = 0.0821 L atm K ⁻¹ mol ⁻¹]

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11

Which amongst the following options is correct graphical representation of Boyle's Law?

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12

The correct option in which the density of argon (Atomic mass =40 ) is highest

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13

The correct van der Waals equation for 1 mole of a real gas is

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14

Four gas cylinders containing He , N ₂, CO ₂ and NH ₃ gases separately are graudally cooled from a temperature of 500 ~K . Which gas will liquify first ? (Given T _ C in K - He : 5

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15

A vessel contains 3.2 ~g of dioxygen gas at STP (273.15 K and 1 atm pressure). The gas is now transferred to another vessel at constant temperature, where pressure becomes one thir

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16

A 10 . 0   L flask contains 64   g of oxygen at 27 ° C . (Assume O 2 gas is behaving ideally). The pressure inside the flask in bar is (Given R = 0 . 0831   L &

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17

Which one is not correct mathematical equation for Dalton's Law of partial pressure? Here P = total pressure of gaseous mixture

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18

Choose the correct option for graphical representation of Boyle's law, which shows a graph of pressure vs. volume of a gas at different temperatures:

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19

Choose the correct option for the total pressure (in atm.) in a mixture of 4 g   O 2 and 2 g   H 2 confined in a total volume of one litre at 0 ° C is [Given R = 0 .

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20

The minimum pressure required to compress 600   dm 3 of a gas at 1 bar to 150   dm 3 at 40 ° C is

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21

A mixture of N 2 and Ar gases in a cylinder contains 7   g of N 2 and 8   g of Ar . If the total pressure of the mixture of the gases in the cylinder is 27 bar, the parti

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22

Assertion : A spherical water drop becomes flat on flat surface. Reason : It becomes flat due to gravity.

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23

Assertion : Liquefaction of NH ₃ is easier than CO ₂ . Reason : T_c of CO ₂ is more than that of NH ₃ .

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24

Moles of N ₂=0.4 and moles of O ₂=0.1 find p _ N ₂ (Partial pressure) N ₂= ?at atmospherim pressure

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25

In an ideal gas equation which is constant?

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26

If V =1 litre, 10 mole of H ₂ and 10 mole of N ₂ gas are mixed at temperature 26^ C , then calculate pressure of the gas.

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27

A gas at 350   K and 15 bar has a molar volume 20 per cent smaller than that for an ideal gas under the same conditions. The correct option about the gas, and its compressibil

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28

The volume occupied by 1.8 ~g of water vapour at 374^ C and 1 bar pressure will be [Use R =0.083 bar L K ⁻¹ ~mol ⁻¹ ]

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29

Two separate bulbs contain gas A and gas B . The density of gas A is twice as that of B . The molecular mass of A is half as that of B . If temperature is constant, the ratio of th

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30

Assertion : Greater the value of van der Waals' constant ' a ' greater is the liquefaction of gas. Reason : ' a ' indirectly measures the magnitude of attractive forces between the

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31

When 1 ~g of gas A at 4 bar pressure is added to 2 ~g of gas B , the total pressure inside the container becomes 6 bar. Which of the following is true?

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32

Gas in a cylinder is maintained at 10 ~atm pressure and 300 ~K temperature. The cylinder will explode if pressure of gas goes beyond 15 atm. What is the maximum temperature to whic

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33

In van der Waals equation at constant temperature 300 ~K , if a=1.4 ~atm ~L ~mol ⁻² , V=100 ~mL , n=1 ~mole , then what is the pressure of the gas?

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34

A 100 mL flask contained H ₂ at 200 torr, and a 200 mL flask contained He at 100 torr. The two flask were then connected so that each gas filled their combined volume. Assume, no c

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35

Given, van der Waal's constant for NH 3 ,   H 2 ,   O 2 and CO 2 are respectively 4 . 17 ,   0 . 244 ,   1 . 36   and   3 . 59 . Which one of the

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36

The correction factor 'a' to the ideal gas equation corresponds to which of the following?

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37

The density of a gas A is thrice that of a gas B at the same temperature. The molecular weight of gas B is twice that of A . What will be the ratio of the pressures acting on B and

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38

The compressibility of a gas is less than unity at STP, therefore

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39

A 20   litre container at   400   K contains CO 2 g at pressure 0 . 4   atm and an excess of SrO (neglect the volume of solid SrO ). The volume of the container

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40

Assertion : Critical temperature of CO ₂ is 304 ~K , it cannot be liquified above 304 ~K . Reason : At a certain temperature, volume 1 pressure

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41

Temperature of a gas is t ~K . What would be the temperature at which volume and pressure, both will reduced to half of the initial values?

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42

Equal moles of hydrogen and oxygen gases are placed in a container with a pin-hole through which both can escape. What fraction of the oxygen escape in the time required for one-ha

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43

0.40 g of helium in a bulb at a temperature of T ~K had a pressure of p atm. When the bulb was immersed in water bath at temperature 50 K more than the first one, 0.08 g of gas had

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44

Given that the reduced temperature, = T T_C the reduced pressure, = F F_C the reduced volume, = V V_C Thus, it can be said that the reduced equation of state may be given as

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45

A gas such as carbon monoxide would be most likely to obey the ideal gas law at:

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46

Equal masses of H 2 ,   O 2 and methane have been taken in a container of volume V at temperature 27 o C in identical conditions. The ratio of the volumes of gases H 2 : O 2 :

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47

Assertion : At critical point the densities of substance in gaseous and liquid states are same. Reason : Critical temperature is the temperature at which the real gas exhibit ideal

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48

The average kinetic energy of an ideal gas per molecule in SI units at 25^ C will be

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49

What is the density of N ₂ at 227^ C and 5.00 ~atm pressure? ( R =0.082 ~L ~atm ~K ⁻¹ . . mol ⁻¹ )

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50

Assertion : In a pressure cooker, the water is brought to boil. The cooker is then removed from the stove. Now on removing the lid of pressure cooker, the water starts boiling agai

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51

Arrange the following gases in order of their critical temperature. NH ₃, H ₂ O , CO ₂, O ₂

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52

50 ~mL of each gas A and of gas B takes 150 and 200 ~s respectively for effusing through a pin hole under the similar conditions. If molecular mass of gas B is 36 , the molecular m

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53

A certain gas takes three times as long to effuse out as helium. Its molecular mass will be

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54

For real gases van der Waals' equation is written as (p+ a n^2 V^2 )(V-n b)=n R T where, a and b are van der Waals' constants. Two sets of gases are I. O ₂, CO ₂, H ₂ and He II. CH

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55

Equal volumes of two monoatomic gases, A and B , at same temperature and pressure are mixed. The ratio of specific heats (c_p / c_V ) of the mixture will be

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56

In the van der Waals equation, ' a ' signifies

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57

56 g of nitrogen and 96 g of oxygen are mixed isothermally and at a total pressure of 10 atm . The partial pressures of oxygen and nitrogen (in atm) are respectively

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58

By what factor does the average velocity of a gaseous molecule increase when the temperature (in Kelvin) is doubled?

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59

Two gases A and B having the same volume diffuse through a porous partition in 20 and 10 seconds respectively. The molecular mass of A is 49 u . Molecular mass of B will be

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60

A bubble of air is underwater at temperature 15^ C and the pressure 1.5 ~bar . If the bubble rises to the surface where the temperature is 25^ C and the pressure is 1.0 ~bar , what

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61

A gaseous mixture was prepared by taking equal moles of CO and N ₂ . If the total pressure of the mixture was found 1 atmosphere, the partial pressure of the nitrogen ( N ₂ ) in th

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62

Two flasks X and Y have capacity 1 ~L and 2 ~L respectively and each of them contains 1 mole of a gas. The temperatures of the flasks are so adjusted that average speed of molecule

AIIMS 2010 Solution
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63

Equal weight of CO and CH ₄ are mixed together in an empty container at 300 ~K . The fraction of total pressure exerted by CH ₄ is

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64

The density of a gas is found to be 1.56 ~g / L at 745 mm pressure and 65^ C . What is the moleculer mass of the gas?

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65

The pressure exerted by 6.0 ~g of methane gas in a 0.03 ~m ^3 vessel at 129^ C is (Atomic masses : C =12.01, H =1.01 and R =8.314 JK ⁻¹ ~mol ⁻¹ )

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66

The variation of volume V , with temperature T , keeping pressure constant is called the coefficient of thermal expansion ( ) of a gas. i.e., = 1 V ( V T )_P . For an ideal gas is

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67

Assertion : Compressibility factor for hydrogen varies with pressure with positive slope at all pressure. Reason : Even at low pressure, repulsive forces dominate for hydrogen gas

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68

The most probable velocity (in cm / s ) of hydrogen molecule at 27^ C will be

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69

The mean free path of electrons in a metal is 4 10⁻⁸ ~m . The electric field which can give on an average 2 eV energy to an electron in the metal will be in units of V / m :

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70

The energy absorbed by each molecule ( A ₂ ) of a substance is 4.4 10⁻¹⁹ ~J and bond energy per molecule is 4.0 10⁻¹⁹ ~J . The kinetic energy of the molecule per atom will be :

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71

The root mean square speed of the molecules of diatomic gas is (u ). When the temperature is doubled, the molecules dissociate into two atoms. The new rms speed of the atom is

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72

Assertion : If ( H ₂ ) and ( Cl ₂ ) enclosed separately in the same vessel exert pressure of 100 and (200 ~mm ) respectively, their mixture in the same vessel at the same temperatu

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73

A gas mixture contains ( O ₂ ) and ( N ₂ ) in the ratio of (1: 4 ) by weight. The ratio of their number of molecules is

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74

The volume of a gas measured at (27^ C ) and 1 atm pressure is 10 L. To reduce the volume to 2 L at 1 atm pressure, the temperature required is

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75

If a gas expands at constant temperature, it indicates that

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76

In (P ) versus (V ) graph, the horizontal line is found in which ____ exists.

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77

Critical temperatures for (A, B, C ) and (D ) gases are (25^ C , 10^ C ,-80^ C ) and (15^ C ) respectively. Which gas will be liquefied more easily?

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78

Dominance of strong repulsive forces among the molecules of the gas ( Z= compressibility factor)

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79

A certain sample of gas has a volume of 0.2 L measured at 1 atm pressure and 0^ C . At the same pressure but 273^ C , its volume will be :

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80

Assertion : Compressibility factor for hydrogen varies with pressure with positive slope at all pressures. Reason : Even at low pressures, repulsive forces dominate hydrogen gas.

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81

Ratio of molecular weights of A and B is 4 25 then ratio of rates of diffusion will be

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82

a / V ^2 given in van der Waal's equation is for

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83

When the temperature of an ideal gas is increased from 27^ C to 927^ C , the kinetic energy will be

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84

The surface tension of which of the following liquid is maximum?

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85

Assertion : Effusion rate of oxygen is smaller than nitrogen. Reason : Molar mass of nitrogen is smaller than oxygen.

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86

If P is pressure and is density of a gas, then P and are related as

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87

Under which conditions van der Waals real gas acts as an ideal gas?

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88

How do experiments by Boyle demonstrate the compressibility of gases?

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89

What does the Maxwell-Boltzmann distribution of speeds provide information about?

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90

In gravity-free environments, how do drops behave?

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91

What is the condition under which a substance always remains in one phase?

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92

Which gas law is associated with the statement that the product of pressure and volume is constant?

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93

What is the significance of Boyle temperature or Boyle point for real gases?

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94

What disappears at the critical temperature of a substance?

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95

Why are perfectly elastic collisions important for the behavior of gases?

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96

What happens to gases before they reach the temperature of Absolute zero?

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97

What is the mean square speed a direct measure of?

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98

What is the reason for the decrease in viscosity as temperature rises in a liquid?

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99

What does the equation p1V1/T1 = p2V2/T2 represent?

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100

What is the relationship between pressure, volume, temperature, and moles described by the ideal gas equation?

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101

How is surface tension defined in terms of force and length?

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102

What shape satisfies the condition of having the lowest energy state for a liquid?

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103

What does the term "A" represent in the equation F ∝ ηA × du/dz?

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104

At what temperature does the graph of volume vs. temperature (in Celsius) intercept the temperature axis when extended to zero volume for all gases?

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105

If a gas at constant temperature undergoes expansion, what happens to its volume and pressure, according to Boyle's law?

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106

What quantity is required to determine the average translational kinetic energy of a gas particle in a straight line?

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107

By how much does the volume of a gas increase for each degree rise in temperature, according to Charles and Gay Lussac's experiments?

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108

What is the effect of increased temperature on the effectiveness of intermolecular attraction?

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109

What is the rearranged form of the ideal gas equation in terms of density and molar mass?

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110

What happens to real gases when intermolecular forces are practically negligible?

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111

What is the main parameter that affects the distribution of molecular speeds?

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112

What is the relationship between temperature and the distribution of molecular speeds?

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113

What is the mathematical representation of Dalton's law of partial pressure?

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114

In laminar flow, how does the velocity change from one layer to the next as you move away from the fixed surface?

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115

What would happen to gases if there were a loss of kinetic energy during collisions?

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116

What is the primary characteristic of gas particles?

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117

What is the purpose of plotting pV vs. p for gases at constant temperature?

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118

Which gas law describes the relationship between pressure and volume at constant temperature?

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119

What does STP stand for in the context of gases?

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120

How does the most probable speed change with increasing temperature?

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