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JIPMER 2014
Exam
JIPMER
Year
2014
Subject
Chemistry
Chapter
Structure of Atom

JIPMER 2014 · Chemistry · Structure of Atom

An electron is moving in Bohr's fourth orbit. Its de-Broglie wave...

An electron is moving in Bohr's fourth orbit. Its de-Broglie wave length is λ\lambda. What is the circumference of the fourth orbit?

Options

  1. A2λ\frac{2}{\lambda}
  2. B2λ2 \lambda
  3. C4λ4 \lambda
  4. D4λ\frac{4}{\lambda}

Correct answer

C. 4λ4 \lambda

Step-by-step solution

According to Bohr's concept, an electron always move in the orbit with angular momentum (mvr) equal to nh/2πn h / 2 \pi. ∴mvr=nh2π\therefore \quad m v r=\frac{n h}{2 \pi} or r=n2π⋅(hmv)Orr=nλ2πr=\frac{n}{2 \pi} \cdot\left(\frac{h}{m v}\right) Or r=\frac{n \lambda}{2 \pi} (from de-Broglie equation, λ=hmv\lambda=\frac{h}{m v} ) For fourth orbit (n=4)(n=4), r=2λπ∴ Circumference =2πr=2π×2λπ=4λ\begin{gathered}r=\frac{2 \lambda}{\pi} \\ \therefore \text{ Circumference }=2 \pi r=2 \pi \times \frac{2 \lambda}{\pi}=4 \lambda\end{gathered}
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