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KCET2021ChemistryCoordination Compounds

For the crystal field splitting in octahedral complexes,

Options

  1. Athe energy of the e_ g orbitals will decrease by (3/5) _ o and that of the t_ 2 g will increase by (2 / 5) _ o
  2. Bthe energy of the e_ g orbitals will increase by (3 / 5) _ o and that of the t_ 2 g will decrease by (2 / 5) _
  3. Cthe energy of the e_ g orbitals will increase by (3/5) ₀ and that of the t_ 2 g will increase by (2/5) _ o
  4. Dthe energy of the e_ g orbitals will decrease by (3 / 5) _ o and that of the t_ 2 g will decrease by (2 / 5) _

Correct answer

B. the energy of the e_ g orbitals will increase by (3 / 5) _ o and that of the t_ 2 g will decrease by (2 / 5) _

Step-by-step solution

For crystal field splitting in octahedral complexes, the energy of e_ g orbitals will increase by ( 3 5 ) _ o and that of t_ 2 g will decrease by ( 2 5 ) _ o . The splitting of degenerate d -orbital is as follows.

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