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KCET2020ChemistryCoordination Compounds

The coordination number of F e and C o in the complex ions, . Fe ( C ₂ O ₄ )₃ ]³⁻ and [ Co ( SCN )₄ ]²⁻ are respectively

Options

  1. A3 and 4
  2. B6 and 8
  3. C4 and 6
  4. D6 and 4

Correct answer

D. 6 and 4

Step-by-step solution

The coordination number of Fe in [ Fe ( C ₂ O ₄ )₃ ]³⁺ is 6 and Co in [ Co ( SCN )₄ ]²⁻ is 4 . It is because C ₂ O ₄ is a bidentate ligand. So, 3 2=6 SCN is a monodendate ligand 4 1=4 So, depending upon the number of the ligands, we can calculate the coordination number of central metal atom.

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