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KCET2018ChemistryCoordination Compounds

The IUPAC name of ( [ Co ( NH ₃ )₄ Cl ( NO ₂ ) ] Cl ) is

Options

  1. Atetraammine chloridonitrito - N - cobalt(III) chloride
  2. Btetraammine chloridonitrocobalt (II) chloride
  3. Ctetraammine chloridonitrocobalt (I) chloride
  4. Dtetraammine chloridodinitrocobalt (III) chloride

Correct answer

A. tetraammine chloridonitrito - N - cobalt(III) chloride

Step-by-step solution

The oxidation number of Co in given complex is x+4 0+1(-1)+1(-1)=+1x=+3 The IUPAC name of the given complex [ Co ( NH ₃ )₄ Cl ( NO ₂ ) ] Cl is tetraamminechloridonitrito-N-cobalt(III) chloride. NO ₂⁻ is an ambidentate ligand name is nitrito-N means linkage is from N atom

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