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KCET2011Chemistrys Block Elements

Identify B and D in the following sequence of reactions.

Options

  1. Amethanol and bromoethane
  2. Bethyl hydrogen sulphate and alcoholic KOH
  3. Cethyl hydrogen sulphate and aqueous KOH
  4. Dethanol and alcoholic KOH

Correct answer

D. ethanol and alcoholic KOH

Step-by-step solution

CH ₂= CH ₂ Conc. H ₂ SO ₄ CH ₃- (A) - CH ₂- HSO ₄ (addition reaction) CH ₃- CH ₂- HSO ₄ , H ₂ O CH ₃- (B) CH ₂- OH (hydrolysis) CH ₃- CH ₂- OH PBr ₃ CH ₃ (c) - CH ₂- Br (bromination) CH ₃- CH ₂- Br Alc . KOH ( ) ( ) CH ₂= CH ₂ (dehydrohalogenation) Hence, B and D in the above given reactions are CH ₃ CH ₂ OH (ethanol) and alc. KOH .

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