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AP EAMCET201823 Apr 2018Morning ShiftChemistrys Block ElementsActual

Be and Al show similarities in properties due to diagonal relationship except in the property X given below. What is X ?

Options

  1. ABoth form basic oxides and hydroxides
  2. BIons of both have strong tendency to form complexes
  3. CIn vapour phase chlorides of both have Cl ⁻ bridged chloride structure
  4. DChlorides of both are soluble in organic solvents

Correct answer

C. In vapour phase chlorides of both have Cl ⁻ bridged chloride structure

Step-by-step solution

The oxides and hydroxides of both Be and Al are amphoteric and dissolve in sodium hydroxide solution as well as in hydrochloric acid. aligned & BeO +2 HCl BeCl ₂+ H ₂ O & BeO +2 NaOH Na ₂ BeO ₂+ H ₂ O & Al ₂ O ₃+6 HCl 2 AlCl ₃+3 H ₂ O & Al ₂ O ₃+2 NaOH 2 NaAlO ₂+ H ₂ O aligned

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