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KVPY2011ChemistryCoordination Compounds

The hybridizations of Ni ( CO )₄ and Cr ( H ₂ O )₆²⁺ , respectively, are

Options

  1. Asp ³ and d ³ sp ²
  2. Bdsp ² and d ² sp ³
  3. Csp ³ and d ² sp ³
  4. Ddsp ² and sp ³ ~d ²

Correct answer

C. sp ³ and d ² sp ³

Step-by-step solution

Ni ( CO )₄ Ni ⁰=3 ~d ⁸ 4 ~s ² By effect of S.F.L. CO . [ Cr ( H ₂ O )₆ ]⁺² Cr ⁺²=3 ~d ⁴ 4 ~s ⁰ 4 p ⁰

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