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Manipal MET2012ChemistryCoordination Compounds

The oxidation number of sulphur in H ₂ ~S ₂ O ₈ is

Options

  1. A+2
  2. B+6
  3. C+4
  4. D+7

Correct answer

B. +6

Step-by-step solution

20-atoms are in peroxide linkage Their oxidation state =-1 and, oxidation state of remaining 60 -atoms, =-2 Oxidation state of H -atoms =+1 Let oxidation state of S atom =x aligned & S ₂ H ₂ O ₆ O ₂ & 2 x+2(+1)+6(-2)+2(-1)=0 & 2 x+2-12-2=0 & x=+6 aligned

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