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Manipal MET2018ChemistryCoordination Compounds

Low spin complexes are generally formed by elements of

Options

  1. A3d series
  2. B4 d series
  3. C5 d series
  4. DBoth (2) and (3)

Correct answer

D. Both (2) and (3)

Step-by-step solution

As the crystal field splitting in case of complexes of metal ions in 4 d and 5 d transition series are much larger,the electrons of the metal ion are paired up first in lower energy set of orbitals before going to the higher energy set within the same d -subshell causing maximum pairing and thus, low spin (or spin paired) complexes are formed.

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