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Manipal MET2021Chemistryd and f Block Elements

3.92 g of ferrous ammonium sulphate crystals are dissolved in 100 mL of water, 20 mL of this solution requires 18 mL of KMnO ₄ during titrating for complete oxidation. the weight of KMnO ₄ present in one liter of solution is :

Options

  1. A3.476 g
  2. B12.38 g
  3. C34.76 g
  4. D1.238 g

Correct answer

A. 3.476 g

Step-by-step solution

Normality of salt solution = 3.92 392 1 100 1000=0.1 ~N 20 mL of 0.1 N salt solution 18 ~mL of KMnO ₄ solution 20 mL of 0.1 N salt solution 18 ~mL of KMnO ₄ solution Normality of KMnO ₄ solution = 20 0.1 18 array r Normality of KMnO ₄ solution = 20 0.1 18 = 1 9 ~N array aligned Strength of KMnO ₄ solution & = 1 9 31.6 & =3.5 ~g ~L ⁻¹ aligned

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